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The standard enthalpy of formation of 1,2,3,4-tetrachlorodibenzo-p-dioxine

✍ Scribed by V. A. Luk’yanova; T. S. Papina; V. P. Kolesov; N. V. Chelovskaya; A. N. Fedotov; P. I. Dem’yanov; N. V. Avramenko; V. P. Vorob’eva

Book ID
110183552
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2007
Tongue
English
Weight
167 KB
Volume
81
Category
Article
ISSN
0036-0244

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The standard molar enthalpy of combustion of crystalline 2,3-dichlorodibenzo-p-dioxin was T . y1 Ž . determined by rotating-bomb calorimetry: ⌬ H s y 5406.4 " 6.6 kJ mol . Using this c m T . y1 Ž . result and the standard molar enthalpy of sublimation, ⌬ H s 108.6 " 1.0 kJ mol , sub m the values of

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The standard molar energy of combustion of crystalline 2-chlorodibenzo-p-dioxin was determined by rotating-bomb calorimetry: DcU°m = -(5573.622.8) kJ•mol -1 . The standard molar enthalpy of sublimation was measured in a Calvet microcalorimeter: DsubH°m = (97.2420.55) kJ•mol -1 . Using these results,