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The standard enthalpies of formation of MO(s), MCl2(s), and M2+(aq, ∞) (M = Ba, Sr)

✍ Scribed by E.H.P. Cordfunke; R.J.M. Konings; W. Ouweltjes

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
354 KB
Volume
22
Category
Article
ISSN
0021-9614

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Standard molar enthalpies of formation o
Standard molar enthalpies of formation of PrO2and SrPrO3: the unusual thermodynamic stability of APrO3(A = Sr, Ba)
✍ S.A. Gramsch; L.R. Morss 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 423 KB

The standard molar enthalpies of formation DfH°m of the fluorite oxide PrO2 and the perovskite oxide SrPrO3 have been determined by solution calorimetry. A combination of appropriate thermodynamic cycles leads to the values DfH°m(PrO2, 298.15 K)=-(959.824.1) kJ•mol -1 and DfH°m(SrPrO3, 298.15 K)=-(1