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The stabilization of LiAsF6/1,3-dioxolane for use in rechargeable lithium batteries

✍ Scribed by J.L. Goldman; L.A. Dominey; V.R. Koch

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
270 KB
Volume
26
Category
Article
ISSN
0378-7753

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✦ Synopsis

The use of highly conductive LiAsFdl,3-dioxolane (DIOX) electrolytes in rechargeable Li batteries is precluded by the ease with which this electrolyte undergoes polymerization. By adding 0.5 -1.0 vol.% 2-methylfuran (2-MeF) to LiAsFdDIOX electrolytes, excellent shelf and cycle life may be obtained in Li/Ti& cells. Stability tests indicate that 2-MeF acts on the TiS2 cathode and the bulk electrolyte as well as on the Li anode.

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