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The stabilization of .alpha.-substituted oxy- and thiocarbanions

โœ Scribed by Bernardi, Fernando.; Bottoni, Andrea.; Venturini, Alessandro.; Mangini, Angelo.

Book ID
127210524
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
647 KB
Volume
108
Category
Article
ISSN
0002-7863

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D-orbital effects and the structure of t
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โœ Saul Wolfe; Lawrence A. LaJohn; Fernando Bernardi; Angelo Mangini; Glauco Tonach ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 294 KB

Improved computational results show that sulfur-3d orbital effects are essential for the nroner descrintion of the bonding in the aloha-thiocarbanions -CHzSH and -CH2SCHs. The nature of I . the d-orbital effects has been analyzed, and reasons for the earlier failures to find these effects have been