Richard S. Herrick' and paul J. Botelho Department of Chemistry. College of the Holy Cross, Worcester, Massachusetts, 01610 Received October 12, 1991; accepted January 22, 1992 Equilibrium constants between \(3.9(1.2) \times 10^{3}\) and \(7.3(1.7) \times 10^{4} \mathrm{M}^{-1}\) are reported for
The Stability of the Oxidation State +4 in Group 14 Compounds from Carbon to Element 114
β Scribed by Michael Seth; Knut Faegri; Peter Schwerdtfeger
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 111 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The mono-and bidentate chelation of the main-group related bis(diamino)-and the higher element homologue bis(diarsanyl)methanide ligand systems have been studied. elements silicon, germanium, tin, and lead through the phosphorus atoms of the diphosphanylmethanide ligand has The bonding situation in
## NMR / Salt metathesis The sodium salts Na 2 [{(CO) 5 M} 2 EX 2 ] (M = Cr, Mo, W; E = compounds (2b, 2c) are able to rotate by a full 180Β°turnaround with respect to one another. This process must Ge, Sn, Pb; X = Cl, I, OOCCH 3 ) react with 2,2'-bipyridine (bipy) to form neutral compounds [{(CO)
AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c