𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Stability of Divalent 3d- and Trivalent 4f-Metal Complexes with Diazapolyoxa Macrocyclic Ligands

✍ Scribed by Giorgio Anderegg

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
337 KB
Volume
64
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The complex formation of some divalent 3d‐ and trivalent 4f‐metal ions with four macrocyclic ligands has been investigated in methanol/water 95:5 by use of alkalimetric titrations. In contrast to alkali and alkaline‐earth cations the obtained stability constants are quite low. The reasons of this effect are discussed.

📜 SIMILAR VOLUMES

Metal complexes with macrocyclic ligands
Metal complexes with macrocyclic ligands. Part XXXVI. Thermodynamic and kinetic studies of bivalent and trivalent metal ions with 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid
✍ Hui-Zhi Cai; Thomas A. Kaden 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 German ⚖ 766 KB

## Abstract NMR, potentiometric, and UV/VIS measurements were run to study the protonation and the In^3+^ and Cu^2+^ stability constants of 1,4,7,10‐tetraazacyclododecane‐1,4,7‐triacetic acid (do3a, L). The protonation of do3a follows the typical scheme with two high and several low log __K__~H~ va

Metal complexes with macrocyclic ligands
Metal complexes with macrocyclic ligands. XIII. The complexation of Cu2+ with triazacycloalkanes
✍ Theodor J. Riedo; Thomas A. Kaden 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 412 KB 👁 1 views

## Abstract The potentiometric study of the complexation of Cu^2+^ with 1,4,7‐triazacyclononane (**1**), 1,4,8‐triazacyclodecane (**2**) 1,5,9‐triazacyclododecane (**3**) has shown that CuL, CuL~2~ and (CuLOH)~2~ are the main species present in solution. Their stabilities (__Table 1__) and their ab