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The spin-orbit interaction in the configuration nlNn'l using nonorthogonal radial orbitals

✍ Scribed by A. P. Jucys; K. V. Sabas; Z. J. Kupliauskis

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
448 KB
Volume
9
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

Formulas for the calculation of matrix elements of the simplified operator of the spin‐orbit interaction for the configuration n~1~l^N^n~2~l are deduced for the case when radial orbitals are nonorthogonal. The coefficients of the radial integrals are tabulated for the configuration p^N^p. The fine structure of the excited configuration of the carbon atom is calculated.

πŸ“œ SIMILAR VOLUMES

Nonorthogonal radial orbitals for the co
Nonorthogonal radial orbitals for the configuration lnl
✍ A. P. Jucys; K. V. Sabas; Z. J. Kupliauskis πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 759 KB

## Abstract The theory of treating the configuration __n__~0~__l____n__~1~__l^N^n__~2~__l__ by means of nonorthogonal radial orbitals is described. The expressions for the matrix elements of the nonrelativistic Hamiltonian are deduced. A table that enables one to obtain these expressions in terms o

On the identification of symmetry-forbid
On the identification of symmetry-forbidden spin subspaces for configurations employing nonorthogonal orbitals
✍ Fabio E. Penotti πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 286 KB

The implications of orbital symmetry for a configuration's spin function are considered from the fairly general viewpoint required for multiconfiguration wave functions employing nonorthogonal orbitals. A general procedure is derived for the imposition of the spin constraints that may be necessary t