The spin density delocalization and the exchange interaction in N,N′-dioxy-2,6-diazoadamantane

✍ Scribed by R.N. Musin; P.V. Schastnev

• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 148 KB
• Volume: 51
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(77)85407-9

✦ Synopsis

The contribution to the exchange integral, resulting from a direct overlap of the n-orbitals of >NO fragments and from the spin density deloca!ization to the adamautane core, has been calculated. The delocalization is of primary importante. in the exchange interaction and does not signify in the spin-spin interaction.