Peak splitting of the S, emission response from sulphur-containing amino acids in molecular emission cavity analysis is investigated. The primary reaction of the compounds in a hydrogen flame is found to be desulphurization by the determination of non-volatile products remaining in a cavity, using l
The spectrographic analysis of solutions by a modified ramage flame emission method
β Scribed by Mitchell, R. L.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1941
- Weight
- 345 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0368-4075
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β¦ Synopsis
Tlic npplicntion of a modified Ramnge flamo method, employing tlic niechnnical feed derim of Stotvnrd nnd Hnrrison, to the estimation of rnrious cations line been studied, nnd working concentrntions suitnblo for routine annlysis linre been determined. The factors which may ennso inncctirncies nro discussed and tho rnotliod is c o i n p n d with tlint of LuntlcgXrdh. ltcsults for tho doterminntion of cnsily soluble soil-potnssium by both ntetltods nro quoted. Approximately cqiinl nccurncy was obtnincd from duplicntes by tho Luntlegkrdh mctliod ond quadruplicates by the mollified Rninnge mothod. It is pointed out t h t in tho pliotoiuetric evnluntion of flnnio spectrogrnms, tho use of tho rntio rntlicr tlinn tho difference of ntensurements of lino and background densities is prefernble.
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