The spectra and stabilities of alkoxyl-substituted phthalocyaninatometals: I. The effect of axial coordination abilities of the center metals on their stabilities in benzoyl peroxide

✍ Scribed by Mei-Jin Lin; Liang Yang; Jun-Dong Wang

• Publisher: Elsevier Science
• Year: 2007
• Tongue: English
• Weight: 540 KB
• Volume: 273
• Category: Article
• ISSN: 1381-1169
• DOI: 10.1016/j.molcata.2007.04.006

✦ Synopsis

The stabilities of phthalocyaninatometals are reduced seriously by the substitution of bulky alkoxyl substituents. In the toluene, tetra-␣-(2,2,4trimethyl-3-pentoxy)phthalocyaninatometals can be decomposed by the benzoyl peroxide, and the order of decomposition rate sorted with the center metals is Fe > Co > Cu > Ni > Pd, which showed a consistency with the axial coordination abilities of the center metals.