𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The specific adsorption of cyclohexane and benzenesulfonate anions at a mercury electrode

✍ Scribed by Edward Dutkiewicz; Jolanta Stuczyńska

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
507 KB
Volume
33
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

The specificadsorption ofcyclohexaneand benzenesulfonate anions has been studied from mixed electrolyte solutions at constant ionic strength at a mercury electrode. The adsorption can be described by a virial adsorption isotherm. The role of the rc-electrons in the adsorption process and the charge dependence of the standard Gibbs energy is discussed. The influence of conformational properties of cyclohexanesulfonate anion on the structure of the inner double layer is also considered.

📜 SIMILAR VOLUMES

Adsorption and reduction of m-nitropheno
Adsorption and reduction of m-nitrophenol at the dropping mercury electrode
✍ D. Britz; H.H. Bauer 📂 Article 📅 1968 🏛 Elsevier Science 🌐 English ⚖ 862 KB

m-Nitrophenol is adsorbed at the dme, and lowers the double-layer capacitance, at potentials more positive than its reduction potential. At that potential, a differential-capacitance peak appears that is partly faradaic in origin and partly due to the "desorption" (through reduction) of the m-nitrop