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The solvent effect on the IR absorption band of hydrogen chloride in the free state and hydrogen bonded to acetone and acetonitrile.

✍ Scribed by Bozena Pedzisz; Rudolf Konopka

Publisher: Elsevier Science
Year: 1978
Weight: 673 KB
Volume: 12
Category: Article
ISSN: 0378-4487
DOI: 10.1016/0378-4487(78)80005-3

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✦ Synopsis

The effect of solvent on the vs frequency of the IR absorption band for hydrogen chloride and hydrogen bonded hydrogen chloride was studied.

Applying the Bakhshiev method of studing the Van der Waals interaction effect on molecular absorption spectra, the theoretical values of vsHCl were computed for various solvents.

By comparing the experimental and theoretical data the effect of solvent on the vs frequency of "bonded" hydrogen chloride in the systems studied was shown to arise from Van der Waals interactions between the hydrogen chloride molecule and its second salvation shell.

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