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The solid state and solution conformation of 1,2-o-alkylidene-α-D-ribopyranoses. Chirality assessment of pentoses from crystallograph

✍ Scribed by Felix H. Cano; C. Foces-Foces; Jesus Jimenez-Barbero; Antonio Alemany; Manuel Bernabe; Manuel Martin-Lomas


Book ID
107857358
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
762 KB
Volume
42
Category
Article
ISSN
0040-4020

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Conformational difference in the solid s
✍ Masataka Mori; Tatsuji Chuman; Takane Fujimori; Kunio Kato; Akira Ohkubo; Shozo 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 479 KB

The conformational difference of the title compound (1) in the solid state and in solution has been investigated by X-ray crystallography and high-field proton n.m.r. spectrometry. In the solid state, compound 1 adopts the "c,(D) conformation (la), whereas 1 exists preferentially in the 'C4(D) confo