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The solid solution and magnetic properties of (Mg, Cu)3 (PO4)2 phosphates

✍ Scribed by A. Moqine; A. Boukhari; S. Flandrois

Book ID
113187444
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
340 KB
Volume
22
Category
Article
ISSN
0025-5408

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New phosphates, Sr1.9Cu4.1(PO4)4, Sr2Cu(PO4)2, and Sr9.1Cu1.4(PO4)7, were found in the Cu3(PO4)2+Sr3(PO4)2 system at 9003C under air. Sr1.9Cu4.1(PO4)4 crystallizes in an orthorhombic system with a ‫؍‬ 15.3695(7) A > , b ‫؍‬ 10.3652(4) A > , and c ‫؍‬ 7.9425(4) A > . Crystal structures of Sr9.1Cu1.4(

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The crystal structure of \(\mathrm{BaCu}_{2}\left(\mathrm{PO}_{4}\right)_{2}\) has been determined from X-Ray single crystal data. The crystal symmetry is triclinic, space group \(P \overline{1}\), with unit celt constants \(a=9.226(1) \AA, b=9.271(1) \AA, c=\) 10.516(1) \(\AA, \alpha=106.76(5)^{\ci