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The solid-gas chlorination and bromination of a fluorinated olefin

✍ Scribed by Douglas G Naae

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
182 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis

The solid-gas reactions of bromine or chlorine with crystalline olefins have been 1 reported only occasionally until the last few years . Recent work has been dIrected at understanding the influence of the crystal lattice upon the course of these re-actionszm4. Some systems have showed relatively highsolid phasereactivity, even in the dark?.

Because of this increased reactivity it was of interest to determine if crystalline polyfluorinated olefins would also exhibit high solid-state reactivity toward chlorine and bromine. The usual solution reaction conditions for the chlorination or bromination of fluorinated olefins favor a radical reaction'. Thus, the solid-gas reaction of E-(4-biphenylyl)-F-propene,>, with chlorine and bromine was studied to determine its reactivity relative to solution reactions.

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