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The Sodium—Ammonia Reduction of Bispropargyl- and Propargylallylamines. Steric and Conformational Effects 1

✍ Scribed by Hennion, G. F.; Ode, R. H.

Book ID
121417395
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
444 KB
Volume
31
Category
Article
ISSN
0022-3263

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Steric Effects in the Reduction of Keton
Steric Effects in the Reduction of Ketones with Sodium Borohydride
✍ Paul Müller; Jean-Claude Perlberger 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 267 KB

## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from force‐field calculations; __i.e.__ the strain difference between alcohol and ketone (Δ strain) and the steric hindrance towards approach of the hydride R. Models