Part 24 of the series 'High-pressure NMR Kinetics'. Part 23: [I]. These results are part of the Ph. D. thesis of A .
The Slowest Water Exchange at a Homoleptic Mononuclear Metal Center: Variable-Temperature and Variable-Pressure 17 O NMR Study on [Ir(H 2 O) 6 ] 3+
✍ Scribed by Cusanelli, Antonio; Frey, Urban; Richens, David T.; Merbach, André E.
- Book ID
- 120930973
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 209 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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## Abstract ^17^O NMR longitudinal and tranverse relaxation rates and chemical shifts were measured at variable temperature at three magnetic fields (1.4, 4.7 and 9.4 T) for aqueous solutions of the complexes [Gd(H~2~O)~8~]^3+^ and [Gd(PDTA)(H~2~O)~2~]^−^. The transverse relaxation rates and chemic
## Abstract ^17^O NMR relaxation rate measurements were made on aqueous perchlorate solutions of the light lanthanide ions Nd^3+^ and Pr^3+^, with the aim of measuring the kinetics of water exchange on these ennea aqua ions. Variable‐temperature results at three magnetic fields show that the ‘kinet