2 reacts with fluorosilanes, e.g. with F3SiC6H5, in the molar ratio 1 2 to give disubstituted ("monomeric") products containing an eight-membered ring. ['] Reaction in the molar ratio 1 : 1 leads to a derivative 4 of the novel bicyclic system 1,3,5,7-tetraaza-2,4,6,8,9-pentasilabicyclo[3.3.l]nonane
โฆ LIBER โฆ
The SiSi Group as a Structural Unit in Open-Chain and Cyclic Phosphorus Ylides
โ Scribed by Prof. Dr. Hubert Schmidbaur; Dipl.-Chem. Wolfgang Vornberger
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 234 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c