The simulation of the homogeneous catalytic reaction at a monolayer-film covered rotating disc electrode

✍ Scribed by Milivoj Lovrić; Marko Branica

• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 616 KB
• Volume: 28
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(83)85014-2

✦ Synopsis

A simple and fast numerical method for the simulation of linear scan voltammetric response of the homogeneous catalytic reaction al the electroactive-monolayer-fitm covered rotating&c electrodes has been developed. The linear relationship between the vohammetric peak current and the concentration of dissolved reactant ions has been predlltecl. The proportionality factor of this relationship is very similar to the one predicted for steady-state conditions. The voltammetric peak current is, also, tinenrly proportional to the square roots of scan rate and rotation rate of the disc electrode, but no cumulative relationship on these parameters is predicted.