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The simulation of hydrolytic polymerization of ε-caprolactam in various reactors: A simulation model for the tubular reactor with heat exchanger and its numerical solution

✍ Scribed by Kazuo Tai; Yoshihiro Arai; Takashi Tagawa


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
634 KB
Volume
28
Category
Article
ISSN
0021-8995

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✦ Synopsis


A concrete simulation model which deals with the hydrolytic polymerization of c-caprolactam (CL) in the tubular reactor (TR) with the heat exchangers (HEx's) was described, and a method for its numerical solution was presented. The numerical calculations were carried out for 13 cases, where the position and number of the HEx's in the T R were varied. The effects of the HEX on the distribution of the temperature in the T R and of the characteristic data of the polymerization (the concentration of CL and number average degree of polymerization) in the T R and a t the outlet of the T R were investigated. The results suggested that the HEX positioned a t the upper half of the T R and the HEX positioned a t the lower half of the T R are effective to narrow the temperature distribution in the T R and to produce the polymer product with narrower molecular weight distribution, respectively.