Reports from many laboratories have documented the capability of transition metal ions and complexes to induce rearrangements of the bicyclobutane skeleton and of many other strained l-6 hydrocarbons . The state of the art has now reached a level where the applications are of syn-
✦ LIBER ✦
The silver ion promoted valence isomerization of 1,1′-dimethylbicyclopropenyl.
✍ Scribed by W.H. de Wolf; J.W.v. Straten; F. Bickelhaupt
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 124 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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Previous studies in our laboratory have illustrated the utility of cyclopropene derivatives in the synthesis of substituted cycloheptatrienes.(2) As a logical extension of this work we have examined the reaction of several cyclopropenes with heterocyclic dienes in the hope of obtaining convenient s