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The Silane-ene and Silane-Acrylate Polymerization Process: A New Promising Chemistry?

✍ Scribed by Mohamad El-Roz; Jacques Lalevée; Xavier Allonas; Jean-Pierre Fouassier

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
120 KB
Volume
29
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

The combination of silanes and enes yields highly reactive photopolymerizable mixtures that exhibit very low oxygen sensitivity. Diphenylsilane (SiH) has been used in combination with different multifunctional acrylates (AC) and conversions of 100% and about 25% for AC and SiH, respectively, have been reached. Final tack free polymers are obtained as a consequence of the fact that the polymerization rates are not affected by oxygen. When using vinylacetate (VA), divinylether (DVE), and allylether (AE) units, the final silane conversion still remains low (50, 20, and 20%, respectively) but are promising. The reactivity of the silyl radicals is investigated by laser flash photolysis. The role of the bond dissociation energy of the silane is outlined.

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✍ Shanhua Zhou; Yan Gao; Yantao Wang; Chunpu Hu; Qingzhi Dong 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 325 KB

## Abstract Styrene/tetradecyl methyl acrylate/3‐methacryloxylpropyl trimethoxyl silane triblock copolymers (PSTKs), with well‐defined structures and narrow molecular weight distributions, were synthesized by atom transfer radical polymerization. They were investigated as macromolecular coupling ag