## Abstract Branched poly(butyl acrylate) was obtained from pulsedโlaser polymerizations carried out in bulk and in solution between โ16 and 60โยฐC. The predominantly short branches are formed by backbiting. The Arrhenius temperature dependence of the backbiting rate is calculated, and the activatio
The significance of transfer reactions in pulsed laser polymerization experiments
โ Scribed by Markus Busch; Almut Wahl
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 788 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1022-1344
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## Abstract The molecularโweight distribution (MWD), obtained by pulsed laser polymerization (PLP) at the high termination rate limit has been considered for investigating termination kinetics. The proposed methodology takes into account both the composite model for termination and the chainโlength
## Abstract The Monte Carlo method has been used for numerically simulating pulsedโlaser polymerization (PLP) in microemulsion, in order to establish if a shift from inflection point to peak maximum as the best measure of the propagation rate constant, __k__~p~, will occur theoretically. Terminatio