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The significance of field ionisation kinetics to ion structure: Isomerisation and decompostition of [C4H8]+· radical ions

✍ Scribed by Roger P. Morgan; Peter J. Derrick


Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
850 KB
Volume
10
Category
Article
ISSN
1076-5174

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip