The electron spin polarization pattern observed in independently generated radicals (F-pairs) produced by both laser photolysis and puls e radiolysis in water, alcoholic, and hydrocarbon solvents is E/A, low-field emission, high-field enhanced absorption. Thus, the sign of the exchange coupling in F
The sign of the electron exchange interaction in binuclear vanadyl tartrate
โ Scribed by M. Guerra; G.F. Pedulli; G.R. Luckhurst
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 310 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
An analysis of the asymmetric line broadening in the solution electron resonance spectrum ofvanadyl tartrata demonstrates that the cschangc interaction is positive. The scparrttion between the two vonadyl units is shown to increase slightly when the complcs passes from a solid to 3 fluid solution.
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