The short-range component of surface-enhanced Raman scattering: thiourea adsorbed on a silver electrode
β Scribed by S.H. Macomber; T.E. Furtak
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 412 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The short-range component of SERS IS tnvcstigated usu-~g a new probe molecule, lhlourca Through a study of the chxactcnstics or thiourea ndsarbcd on a sliver clectrodc we conclude that remnant surFace complexes arc not a un~vcrul rcquircment for large enhancement. We lurther show that the npphul voltage deriitely influcnccs the cnhanccmcnt Tar irdlvidual thlourca molecules 1 Inboductlon Several aspects of surfaceenhanced Raman scattering (SERS) are not yet resolved. Although electromagnetic field enhancement, which influences molecules some distance away from the metal surface, can be
π SIMILAR VOLUMES
SERS from crystal rlolct (CV) on a Ag clectrodc was mvcslqakd under prcrrsonsncc and resonance condltlons. The ckcll~llon prolilc of the chcmaorbcd spccics is Me that of chsrolvcd mokculcs but mtcnsltirs ZUIL' =I000 tnncs luger. The Raman enhancement IS = IO8 and ckhlblts 3 spcc~lic potcntlal dcpcnd
The surface-enhanced Raman (SER) scattering of p-nitroaniline adsorbed on silver colloids was investigated and compared with previous results obtained on a silver electrode. The SER spectra change signiΓcantly on varying the pH of the colloidal dispersions and correspond to di β erent adsorbed specie