The shape and width of resonance Raman spectral lines

✍ Scribed by J. Behringer

• Publisher: John Wiley and Sons
• Year: 1975
• Tongue: English
• Weight: 852 KB
• Volume: 4
• Category: Article
• ISSN: 0377-0486
• DOI: 10.1002/jrs.1250040203

✦ Synopsis

Abstract

Presupposing exponentially decaying states (with phenomenological lifetimes) of the particle system interacting with the radiation field, the shape and width of Raman lines is discussed on a quantum‐mechanical basis for the most important types of excitation: non‐resonance, pre‐resonance, rigorous resonance with a continuum level and with a discrete, non‐degenerate, and isolated level; monochromatic and non‐monochromatic irradiation. Attention is called to peculiar intensity distributions of the secondary radiation obtainable by sufficiently monochromatic excitation in near resonance to an isolated state (resonance fluorescence case) which deviate characteristically from those customary in traditional fluorescence and scattering spectra.