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The sequential reactions of tetrazoles with bromoalkynes for the synthesis of (Z)-N-(2-bromo-1-vinyl)-N-arylcyanamides and 2-arylindoles

✍ Scribed by Zhang, Jiajun; Meng, Ling-Guo; Li, Pinhua; Wang, Lei


Book ID
120090197
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
677 KB
Volume
3
Category
Article
ISSN
2046-2069

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DMF-induced reaction of [(Z)-1-bromo-1-alkenyl]dialkylboranes with an N-halogeno compound results in 1,2migration of an alkyl group from the dialkylboryl group to the Ξ±-carbon atom without elimination of the bromine atom, followed by Ξ²-elimination to provide 1,2-disubstituted (E)-vinyl bromides ster