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The separation and determination of low-molecular-weight (C2—C10) straight-chain carboxylic acids in dilute aqueous solution by the gas chromatography of their p-bromophenacyl and P-phenylphenacyl esters

✍ Scribed by E.O. Umeh


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
578 KB
Volume
56
Category
Article
ISSN
1873-3778

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✦ Synopsis


The quantitative and qualitative analysis of acetic, propionic, m-butyric, nvaleric, rt-hexoic, +z-heptoic, a-octoic, ?+nonoic and rt-decanoic acids present in dilute aqueous media as free acids or salts, in the presence of mineral acids or bases, is described. The +bromophenacyl or $-phenylphenacyl esters of the acids were formed and injected into 2.5 o/o sodium dodecylbenzene sulphonate or I o/o Apiezon L or a I : I mixture of the two (depending on which acids were present) coated on acidwashed Go/So mesh Chromosorb G packed in a 6-ft. glass column.