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The self-consistent determination of ion-pair distribution functions within the Debye-Hückel framework

✍ Scribed by I.L. Cooper; J.A. Harrison

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 504 KB
Volume: 111
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85545-1

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✦ Synopsis

Pair distribution functions for like ions in an electrolyte are generally predicted by the traditional Dcbye-Hiickel model to be unphysical, becoming negative at small sepamtions from the reference ion A simple modiication to the Debye-Hiickel model is proposed which corrects this unphysical bchaviour while retaining both the linearity and overall charge ncutr.rlity of the model.

📜 SIMILAR VOLUMES

An improved procedure for the constructi

An improved procedure for the construction of ion-pair distribution functions within the Debye-Hückel framework

✍ I.L. Cooper; J.A. Harrison 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 387 KB

A rccen~ly proposed scheme Ior rhs conslrucrion of physicolly realiskz pair functions Tar Ihc dislrihurion of ions about a centrd rderence ion within the rramcwork or Ihc Dcbyc-Huckel model is assessed and uxwndcd LC, include Ihs clrscls or dirkrem disunces or closest approach Tar !ilic end unlik io