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The Seeded Growth of Calcium Sulfate Dihydrate Crystals in NaCl Solutions up to 6 m and 90°C

✍ Scribed by Shiliang He; John E. Oddo; Mason B. Tomson


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
303 KB
Volume
163
Category
Article
ISSN
0021-9797

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✦ Synopsis


The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in (\mathrm{NaCl}) electrolyte solutions from 0 to (6 m) at temperatures of (25,50,70), and (90^{\circ} \mathrm{C}). The growth followed a second-order parabolic rate law with activation energies greater than (53 \mathrm{~kJ} / \mathrm{mol}) which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with (\mathrm{NaCl}) concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from (61 \mathrm{~kJ} / \mathrm{mol}) in the pure (\mathrm{Ca}-\mathrm{SO}{4}-) (\mathrm{H}{2} \mathrm{O}) system to (53 \mathrm{~kJ} / \mathrm{mol}) in (3.0 \mathrm{~m} \mathrm{NaCl}) solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous clectrolyte solutions resulting from the variation of the mean activity coefficient of the crystal with ionic strength. The rate constant is proportional to the crystal solubility and inversely proportional to the edge work or the interfacial tension as expected in the classic BCF model. 1994 Academic Press, Inc.


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