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The Scope and Limitations of Intramolecular Nicholas and Pauson−Khand Reactions for the Synthesis of Tricyclic Oxygen- and Nitrogen-Containing Heterocycles

✍ Scribed by Closser, Kristina D.; Quintal, Miriam M.; Shea, Kevin M.

Book ID
115453354
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
495 KB
Volume
74
Category
Article
ISSN
0022-3263

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✍ Marta Rosillo; Eduardo Arnáiz; Delbrin Abdi; Jaime Blanco-Urgoiti; Gema Domíngue 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB

## Abstract The combination of ring‐closing metathesis (RCM) followed by an intramolecular Pauson–Khand reaction gives direct entry to tricyclic compounds. The RCM was carried out on a hexacarbonylcobalt‐complexed alkyne, this complex acting as a protecting group against enyne metathesis. The proce