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The scaling behavior of the molecular parameters of the hyperbranched polymers made by self-condensing vinyl polymerization

✍ Scribed by X. W. Ba; Y. L. Tian; J. Z. Diao; S. J. Wang; H. J. Wang

Book ID: 111632034
Publisher: Springer-Verlag
Year: 2005
Tongue: English
Weight: 81 KB
Volume: 17
Category: Article
ISSN: 1292-8941
DOI: 10.1140/epje/i2004-10140-y

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## Abstract Hyperbranched copolymers were synthesized by self‐condensing vinyl copolymerization (SCVCP) of 2‐[(2‐bromopropionyl)oxy]ethyl acrylate (BPEA) and methyl acrylate (MA) in the presence of a tetrafunctional initiator, 6,6‐bis[5‐(α‐bromoisobutyryloxy)‐2‐oxapentyl]‐4,8‐dioxaundecane‐yl‐1,11

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The self-condensing vinyl polymerization of 4-(chloromethyl)styrene using metal-catalyzed living radical polymerization catalyzed by the complex CuCl/2,2 -bipyridyl has been attempted. Given the unequal reactivity of the two potential propagating species in this system, a variety of polymerization c