The saponification kinetics of the co-polymer of acrylonitrile with methylacrylate and sodium itaconate
β Scribed by M. P. Mikhailova; P. V. Mikhailov; G. I. Kudryavtsev
- Publisher
- Springer US
- Year
- 1972
- Tongue
- English
- Weight
- 243 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0015-0541
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The phase-transfer radical copolymerization of acrylonitrile (AN) and methylacrylate (MA) with tricaprylylmethylammonium chloride was investigated in Na 2 S 2 O 8 aqueous-organic two-phase system at 25Β°C and under nitrogen atmosphere. The rate of copolymerization was expressed as the combined terms
## Abstract The bulk copolymerizations of acrylonitrile (AN) with vinyl acetate (VAc) initiated by azobisisobutyronitrile (AIBN) and the suspension copolymerization of AN with VAc and sodium methallylsulfonate (SMAS) in water with a Na~2~S~2~O~5~βNa~2~ClO~3~ redox initiator system at 65Β°C, were inv