## Abstract The proton spectrum, including ^13^C satellites at natural abundance, of partially oriented __m__‐dichlorobenzene was analysed. Carbon–carbon, carbon–hydrogen and hydrogen–hydrogen internuclear distance ratios, as well as bond angles were derived and corrected for harmonic vibrations (_
The rα-structure of partially oriented phthalonitrile determined from its proton spectrum with natural abundance 13C- and 15N-satellites
✍ Scribed by P. Diehl; J. Amrein; H. Bösiger; F. Moia
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 182 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The proton spectra of phthalonitrile, including ^13^C‐ and ^15^N‐satellites at natural abundance in isotropic and oriented solvents, have been analysed. The entire r~α~‐structure is derived from the direct couplings. The AISEFT method has been used for obtaining the pure satellite information.
📜 SIMILAR VOLUMES
## Abstract By recording two spectra of the same molecule in different nematic liquid crystals, and analysing the data simultaneously, information has been obtained on the molecular structures of 1,2,4,5‐ (1) and 1,2,3,4‐tetrachlorobenzene (2). Carbon–hydrogen and carbon–carbon internuclear distanc
## Abstract It is demonstrated that in a case where neither the proton nor the natural‐abundance ^13^C‐satellite spectra of a partially oriented molecule carry enough structural information, one can determine the entire molecular geometry by the combined use of several liquid crystals as solvents.