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The rα structure of benzonitrile, determined by NMR of the oriented molecule

✍ Scribed by P. Diehl; J. Amrein; C. A. Veracini

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
218 KB
Volume
20
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The indirect and direct proton–proton, proton–carbon and proton–nitrogen coupling constants of benzonitrile have been measured from proton spectra with natural abundance satellites, and also from proton and ^15^N spectra of the molecule enriched in ^13^C or ^15^N at the cyano group, both in isotropic as well as in oriented solvents. The r~α~ structure of the entire molecule has subsequently been determined.

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