The rotational spectrum of the linear chain molecule tricarbon oxide sulfide, OCCCS, was recorded at room temperature between 118 and 179 GHz using a new commercial millimeter-wave spectrometer. The observed transitions were analyzed together with hitherto unassigned transitions from measurements be
The Rotational Spectrum of Fluoroethyne (HCCF) Revisited
โ Scribed by Aiko Huckauf; Antonio Guarnieri
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 139 KB
- Volume
- 213
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
โฆ Synopsis
The pure rotational spectrum of fluoroethyne (fluoroacetylene, HCCF) has been reinvestigated. Rotational transitions have been measured in the frequency range from 230 up to 510 GHz and assigned to the excited vibrational states (ฯ 3 ฯ 4 ฯ 5 ) = (000), ( 001), ( 002), ( 003), ( 010), ( 011), ( 012), (020), and ( 100). The analysis of the spectrum extends the spectroscopic data for HCCF by correcting and refining the rotational and rovibrational constants determined in our previous investigation.
๐ SIMILAR VOLUMES
In the present work, we study the spectrum of the H 2 Te molecule in the submillimeter-wave and far infrared region. An important aim of this investigation is the further experimental characterization of the anomalous ''four-fold cluster effect'' exhibited by the rotational energy levels in the vibr
The microwave spectra of two isotopic species of \(\mathrm{YCl}\) have been measured using a cavity pulsed microwave Fourier transform spectrometer. The samples were prepared using laser ablation of \(\mathrm{Y}\) metal in the presence of \(\mathrm{Cl}_{2} / \mathrm{Ne}\) mixture and were studied en
The Fourier transform microwave (FTMW) spectra of gaseous monomeric AuF, AuCl, and AuBr have recently been reported (1, 2). Among other things, equilibrium geometries were evaluated, as well as several hyperfine parameters. The Au nuclear quadrupole coupling constants (NQCC) were found to show a mar