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The role of zinc oxide in the vulcanization of rubbers by tetramethylthiuramdisulphide

✍ Scribed by R.Sh. Frenkel; A.S. Kuz'minskii

Book ID
118355851
Publisher
Elsevier Science
Year
1963
Weight
228 KB
Volume
4
Category
Article
ISSN
0032-3950

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## Abstract The vulcanization of rubber by sulfur is a large‐scale industrial process that is only poorly understood, especially the role of zinc oxide, which is added as an activator. We used the highly symmetrical cluster Zn~4~O~4~ (__T__~d~) as a model species to study the thermodynamics of the