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The role of tetraalkylammonium salts in the electro-reduction of ketones III. Pinacolization and asymmetric induction

✍ Scribed by W. J. M. van Tilborg; C. J. Smit

Book ID
104588177
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
562 KB
Volume
98
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES

The role of tetraalkylammonium salts in
The role of tetraalkylammonium salts in the electro-reduction of ketones. I. Competitive adsorption in an aqueous medium
✍ W. J. M. van Tilborg; L. J. G. Dekker; C. J. Smit πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 658 KB

## Abstract Aryl alkyl ketones and tetraalkylammonium ions compete for adsorption in the region where the adsorption voltage ranges of the respective compounds overlap. A study has been made of the effects of changes in structure of the tetraalkylammonium salts as well as of the ketones, of the nat

The role of tetraalkylammonium salts in
The role of tetraalkylammonium salts in the electro-reduction of ketones. Part II: The reduction of acetophenone in an aprotic environment
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## Abstract A polarographic study of the electro‐reduction of acetophenone in dry acetonitrile has revealed that under strictly anhydrous conditions the carbonyl compound can be reduced only if tetraalkylammonium ions are present. The role played by these ammonium ions is discussed. It is concluded