The role of T1 self-quenching in photochemical decay of aromatic thiones
✍ Scribed by Andrzej Maciejewski
- Book ID
- 103991586
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 804 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1010-6030
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The photochemical isomerisatiun of 1,3.5-cycloheptatriene to toluene occurs via the vibrationally excited ground state molecule. Studies of this isomerisation at seven wavelengths and its quenching by various added gases yield values for the vibrational energy removed per collision.
## Abstract The synthesis of five new dihalogen/interhalogen charge transfer adducts featuring cyano and nitro functionalized 1,3‐dithiole‐2‐thiones have been prepared and characterized by x‐ray crystallography. The structures feature a complex series of intermolecular close contacts between hetero