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The role of support in formation of the manganese–bismuth oxide catalyst for synthesis of nitrous oxide through oxidation of ammonia with oxygen

✍ Scribed by A.S Ivanova; E.M Slavinskaya; V.V Mokrinskii; I.A Polukhina; S.V Tsybulya; I.P Prosvirin; V.I Bukhtiyarov; V.A Rogov; V.I Zaikovskii; A.S Noskov

Book ID
113685223
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
761 KB
Volume
221
Category
Article
ISSN
0021-9517

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A series of PbO-MgO aerogels differing by their atomic Pb/Mg ratios were tested at 720°C for methane coupling using nitrous oxide to ethane and ethylene. The best catalyst (Pb/Mg =OS) gave a C,, overall selectivity of 69%, a high activity (at W/F=0.03 g s cm-') and a good stability with time-on-stre