The role of solvent-solute interactions in determining crystal growth mechanisms from solution: I. The surface entropy factor
β Scribed by J.R. Bourne; R.J. Davey
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 894 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-0248
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π SIMILAR VOLUMES
The effect of heat transfer and the role of the surface integration process in crystal growth are analysed quantitatively in terms of a non-isothermal effectiveness factor, defined as the ratio of actual growth rate to the rate that would be obtained if conditions of the supercooled or supersaturate
## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^β1^, Bu~4~N^+^ is the cation) and as βfreeβ (solvated) ion in DMF. The add