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The Role of Secondary Interactions in the Asymmetric Palladium-Catalysed Hydrosilylation of Olefins with Monophosphane Ligands

✍ Scribed by Susan E. Gibson; Matthew Rudd


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
383 KB
Volume
349
Category
Article
ISSN
1615-4150

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## Abstract A new class of chiral __C__~2~‐symmetrical diamino‐oligothiophenes is described to be effective in catalyzing Pd‐mediated asymmetric allylic alkylations in a highly enantioselective manner. The combination of experimental as well as crystallographic evidence revealed the key role played