The role of reagent internal excitation in collision experiments
β Scribed by A. Ben-Shaul; R.D. Levine
- Book ID
- 103016915
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 542 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Variations III the rates of endoergc reactions due to different reagent excitations at the same total energy are of a Iimited (positwe or negative) range and reflect a dynamIcal bias Not so for bulk experiments, where aU non-selected degrees of Geedom have a thermal distriiutton.
π SIMILAR VOLUMES
Exact computations for rotational excitation are compared with the close-coupling approximation and with improved schemes which incorporate adiabatically the closed channels. The "direct ~ transition probability and the resonance energies can be predicted by a modified close-coupling scheme.