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The role of protons in cyclohexene oxidation with H2O2 catalysed by Ti(IV)-monosubstituted Keggin polyoxometalate

✍ Scribed by Oxana A. Kholdeeva; Tatiana A. Trubitsina; Maria N. Timofeeva; Gennadii M. Maksimov; Raisa I. Maksimovskaya; Vladimir A. Rogov


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
167 KB
Volume
232
Category
Article
ISSN
1381-1169

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Kinetics and mechanism of thioether oxid
✍ Oxana A. Kholdeeva; Lyubov A. Kovaleva; Raisa I. Maksimovskaya; Gennadii M. Maks 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 184 KB

Ž . Ž . Kinetics of thioether oxidation with concentrated 86% and diluted 35% aqueous H O in the presence of catalytic 2 2 Ž . Äw x 4 Ž . amounts of Bu N PW O Ti OH dimeric heteropolytungstate 1 has been studied in acetonitrile. With 86% H O the 4 7 11 39 2 2 2 reaction was found to be first order