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The role of protic solvent in asymmetric hydrogenation of methyl levulinate in the presence of a ruthenium-containing catalyst

✍ Scribed by E. V. Starodubtseva; O. V. Turova; M. G. Vinogradov; L. S. Gorshkova; V. A. Ferapontov


Publisher
Springer
Year
2007
Tongue
English
Weight
260 KB
Volume
56
Category
Article
ISSN
1573-9171

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The role of the solvent in the asymmetri
✍ Adi Wolfson; Ivo F.J. Vankelecom; Shimona Geresh; Pierre A. Jacobs πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 103 KB

The influence of the solvent on the asymmetric hydrogenation of methyl acetoacetate, as a representative ␀-keto esters, with Ru-BINAP was studied. The highest activities were measured when the reaction proceeded in methanol, ethanol or isopropanol. These solvents, which also act as proton donors, ac