The absorption, excitation, iluorescence, delayed fluorescence and phosphorescence spectra together with incident light intensity dependence and decay characteristics of the delayed emissions of the proflavine cation in rigid alcoholic solutions are sholvn and analyzed. Evidence for a triplet-triple
The role of photoejected electrons in the delayed fluorescence of indole derivatives in frozen aqueous solutions at 77°K
✍ Scribed by M. Aubailly; M. Bazin; R. Santus
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 480 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
A delayed fluorescence emission of biphotonic nature with the triplet state intermediary is observed from indole ring in low temperature water glasses or in polycrystalline ices. Electron scavengers like CdZ+ions are shown to quench the D.F. emission. A mechanism involving "mobile" electrons or electrons in different solvation states is discussed.
📜 SIMILAR VOLUMES
An opt&fly stimulated delayed fluorescence induced by the nat&C phosphorescence emission is produced after photoionization of indole derivatives in rigid p&u media at 77 K and contributes to the apparent kinetics of the isothermal rccombination flu&escence. : \_.