The role of non-coordinating anions in homogeneous olefin polymerization
β Scribed by Siedle, A. R.; Lamanna, W. M.; Newmark, R. A.; Stevens, J.; Richardson, D. E.; Ryan, M.
- Book ID
- 120835812
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 400 KB
- Volume
- 66
- Category
- Article
- ISSN
- 1022-1360
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π SIMILAR VOLUMES
## Abstract The variations in the microstructure of polydiolefins made with alkali metal catalysts can be adequately explained in terms of the nature of the bond between the metallic catalyst and the growing polymer chain. This bond, in alkali metal polymerization, is not a resonance hybrid of ioni
¨¨à bstract Ž . y wŽ . Ž . q Ž . Displacement of the anion H C-B C F from the zirconocene contact-ion pair C H Zr CH PPP m-H C -3 6 53 5 52 3 3 Ž . y x B C F by a series of phosphines and formation of a bisphosphine complex by uptake of a second phosphine ligand have 6 5 3 been studied by NMR method