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The Role of Molecular Electrostatic Potentials in the Formation of a Halogen Bond in Furan⋅⋅⋅XY and Thiophene⋅⋅⋅XY Complexes

✍ Scribed by Prof. Yanli Zeng; Dr. Xueying Zhang; Dr. Xiaoyan Li; Prof. Lingpeng Meng; Prof. Shijun Zheng


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
526 KB
Volume
12
Category
Article
ISSN
1439-4235

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✍ Christine L. Hannon; Dwayne A. Bell; Anne M. Kelly-Rowley; Larry A. Cabell; Eric 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 3 views

Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho