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The Role of Ligand Density in the Enzymatic Glycosylation of Carbohydrates Presented on Self-Assembled Monolayers of Alkanethiolates on Gold

โœ Scribed by Benjamin T. Houseman; Milan Mrksich


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
127 KB
Volume
38
Category
Article
ISSN
0044-8249

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Long-chain alkanethiols I R(CH,),SH] and substituted phenylthioureas (RPhNHCSNH,) adsorb from solutions on the surface of gold. Analysis by XPS indicates that the binding energies of the S 2p and Au 4d, peaks in alkanethiol monolayers are 162.3 and 335.4 eV, which are 1.4 and 0.4 eV higher than thos